https://ogma.newcastle.edu.au/vital/access/ /manager/Index ${session.getAttribute("locale")} 5 https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:36938 + (0.01 M AgNO₃ in ACN) reference electrode. Situated between the opposing AC electrodes, between two separators, is a Pt sensing electrode, the potential of which is either monitored or controlled to explore either electrolyte fluxes during cycling, or the formation of soluble species in the electrolyte, respectively. It was deduced that electrolyte ions are strongly associated with the AC electrodes rather than between the electrodes even without an applied potential. Furthermore, aging of the electrochemical system with cycling (cyclic voltammetry) is also explored. Even with identical electrodes it is noted that the individual electrodes behaved differently as a result of anion versus cation association. Finally, at cell voltages approaching 2 V, oxidation of the positive electrode is observed, liberating species into the electrolyte. The implications of these observations have been discussed.]]> Tue 21 Jul 2020 11:05:42 AEST ]]> https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:46822 + reference electrode, individual electrode potentials were measured showing that even though it is a symmetrical device, polarization on the positive electrode was always greater than the negative electrode, implying that the negative electrode capacitance is greater. Deconvolution of the i-t transients from the SPECS experiment across the device voltage window can be accomplished in a similar fashion to the study of a single electrode, in which case geometric and porous capacitances, as well as diffusion and residual processes are identified. Similarly, the components of the i-t transients can be converted into voltametric data, providing access to individual electrode performance over a wide range of sweep rates in the device. The inclusion of a sensing electrode between he positive and negative electrodes is also described, providing insight into electrolyte fluxes and electrode stability within the device.]]> Thu 01 Dec 2022 10:00:23 AEDT ]]>